{"id":157,"date":"2014-02-21T10:57:51","date_gmt":"2014-02-21T10:57:51","guid":{"rendered":"http:\/\/ourlocality.org\/mansellresearch\/?page_id=157"},"modified":"2014-02-21T11:43:30","modified_gmt":"2014-02-21T11:43:30","slug":"previous-projects","status":"publish","type":"page","link":"https:\/\/ourlocality.org\/mansellresearch\/previous-projects\/","title":{"rendered":"Previous projects"},"content":{"rendered":"<p><strong>Uranium for small molecule activation<\/strong><br \/>\nUranium-mediated reduction and binding of arenes followed by C-H activation upon addition of a borane (<a href=\"http:\/\/dx.doi.org\/10.1038\/NCHEM.1392\" target=\"_blank\"><em>Nature Chem.<\/em>, <strong>2012<\/strong><\/a>, University of Edinburgh with P. Arnold and L. Maron)<br \/>\n<a href=\"http:\/\/ourlocality.org\/mansellresearch\/files\/2014\/02\/UBBNC6H5.jpg\"><img loading=\"lazy\" decoding=\"async\" src=\"http:\/\/ourlocality.org\/mansellresearch\/files\/2014\/02\/UBBNC6H5-300x240.jpg\" alt=\"UBBNC6H5\" width=\"300\" height=\"240\" class=\"alignnone size-medium wp-image-159\" srcset=\"https:\/\/ourlocality.org\/mansellresearch\/files\/2014\/02\/UBBNC6H5-300x240.jpg 300w, https:\/\/ourlocality.org\/mansellresearch\/files\/2014\/02\/UBBNC6H5-1024x819.jpg 1024w, https:\/\/ourlocality.org\/mansellresearch\/files\/2014\/02\/UBBNC6H5-624x499.jpg 624w\" sizes=\"auto, (max-width: 300px) 100vw, 300px\" \/><\/a><\/p>\n<p>Research into low-valent uranium chemistry that activates dinitrogen, carbon monoxide and carbon dioxide (<a href=\"http:\/\/dx.doi.org\/10.1021\/ja2019492\" target=\"_blank\"><em>J. Am. Chem. Soc.<\/em>, <strong>2011<\/strong>,<\/a> University of Edinburgh, with P. Arnold and N. Kaltsoyannis)<br \/>\n<a href=\"http:\/\/ourlocality.org\/mansellresearch\/files\/2014\/02\/UN2U.jpg\"><img loading=\"lazy\" decoding=\"async\" src=\"http:\/\/ourlocality.org\/mansellresearch\/files\/2014\/02\/UN2U-300x214.jpg\" alt=\"UN2U\" width=\"300\" height=\"214\" class=\"alignnone size-medium wp-image-158\" srcset=\"https:\/\/ourlocality.org\/mansellresearch\/files\/2014\/02\/UN2U-300x214.jpg 300w, https:\/\/ourlocality.org\/mansellresearch\/files\/2014\/02\/UN2U-1024x731.jpg 1024w, https:\/\/ourlocality.org\/mansellresearch\/files\/2014\/02\/UN2U-624x445.jpg 624w\" sizes=\"auto, (max-width: 300px) 100vw, 300px\" \/><\/a><\/p>\n<p><strong>BN containing heterocycles: From analogues of polycyclic aromatic hydrocarbons to persistent radicals<\/strong><br \/>\nSynthesis and characterisation of a persistent boron-containing radical (<a href=\"http:\/\/dx.doi.org\/10.1039\/C0CC00187B\" target=\"_blank\"><em>Chem. Commun.<\/em>, <strong>2010<\/strong><\/a>, University of Bristol, with N. Norman and C. Russell)<br \/>\n<a href=\"http:\/\/ourlocality.org\/mansellresearch\/files\/2014\/02\/rsz_new_cover_radical.jpg\"><img loading=\"lazy\" decoding=\"async\" src=\"http:\/\/ourlocality.org\/mansellresearch\/files\/2014\/02\/rsz_new_cover_radical-300x300.jpg\" alt=\"rsz_new_cover_radical\" width=\"300\" height=\"300\" class=\"alignnone size-medium wp-image-166\" srcset=\"https:\/\/ourlocality.org\/mansellresearch\/files\/2014\/02\/rsz_new_cover_radical.jpg 300w, https:\/\/ourlocality.org\/mansellresearch\/files\/2014\/02\/rsz_new_cover_radical-150x150.jpg 150w\" sizes=\"auto, (max-width: 300px) 100vw, 300px\" \/><\/a><a href=\"http:\/\/ourlocality.org\/mansellresearch\/files\/2014\/02\/EPR_Spectra2.jpg\"><img loading=\"lazy\" decoding=\"async\" src=\"http:\/\/ourlocality.org\/mansellresearch\/files\/2014\/02\/EPR_Spectra2-211x300.jpg\" align=\"center\" alt=\"EPR Spectra\" width=\"211\" height=\"300\" class=\"alignnone size-medium wp-image-164\" srcset=\"https:\/\/ourlocality.org\/mansellresearch\/files\/2014\/02\/EPR_Spectra2-211x300.jpg 211w, https:\/\/ourlocality.org\/mansellresearch\/files\/2014\/02\/EPR_Spectra2-723x1024.jpg 723w, https:\/\/ourlocality.org\/mansellresearch\/files\/2014\/02\/EPR_Spectra2-624x883.jpg 624w, https:\/\/ourlocality.org\/mansellresearch\/files\/2014\/02\/EPR_Spectra2.jpg 1239w\" sizes=\"auto, (max-width: 211px) 100vw, 211px\" \/><\/a><br \/>\n<a href=\"http:\/\/ourlocality.org\/mansellresearch\/files\/2014\/02\/rsz_1rsz_bipbcl2.jpg\"><img loading=\"lazy\" decoding=\"async\" src=\"http:\/\/ourlocality.org\/mansellresearch\/files\/2014\/02\/rsz_1rsz_bipbcl2.jpg\" align=\"center\" alt=\"bipyBCl2 radical\" width=\"124\" height=\"80\" class=\"alignnone size-full wp-image-169\" \/><\/a><\/p>\n<p>Synthesis of a neutral NBN analogue of the aromatic flourenyl anion (<a href=\"http:\/\/dx.doi.org\/10.1039\/C0DT00028K\" target=\"_blank\"><em>Dalton Trans.<\/em>, <strong>2010<\/strong><\/a>, University of Bristol, with N. Norman and C. Russell)<br \/>\n<a href=\"http:\/\/ourlocality.org\/mansellresearch\/files\/2014\/02\/bipyBPh_HOMO_MO64.jpg\"><img loading=\"lazy\" decoding=\"async\" src=\"http:\/\/ourlocality.org\/mansellresearch\/files\/2014\/02\/bipyBPh_HOMO_MO64-300x270.jpg\" alt=\"bipyBPh_HOMO_MO64\" width=\"300\" height=\"270\" class=\"alignnone size-medium wp-image-173\" srcset=\"https:\/\/ourlocality.org\/mansellresearch\/files\/2014\/02\/bipyBPh_HOMO_MO64-300x270.jpg 300w, https:\/\/ourlocality.org\/mansellresearch\/files\/2014\/02\/bipyBPh_HOMO_MO64-624x562.jpg 624w, https:\/\/ourlocality.org\/mansellresearch\/files\/2014\/02\/bipyBPh_HOMO_MO64.jpg 718w\" sizes=\"auto, (max-width: 300px) 100vw, 300px\" \/><\/a><a href=\"http:\/\/ourlocality.org\/mansellresearch\/files\/2014\/02\/New_cover_bipyBPh.jpg\"><img loading=\"lazy\" decoding=\"async\" src=\"http:\/\/ourlocality.org\/mansellresearch\/files\/2014\/02\/New_cover_bipyBPh-300x300.jpg\" alt=\"New_cover_bipyBPh\" width=\"300\" height=\"300\" class=\"alignnone size-medium wp-image-174\" srcset=\"https:\/\/ourlocality.org\/mansellresearch\/files\/2014\/02\/New_cover_bipyBPh-300x300.jpg 300w, https:\/\/ourlocality.org\/mansellresearch\/files\/2014\/02\/New_cover_bipyBPh-150x150.jpg 150w, https:\/\/ourlocality.org\/mansellresearch\/files\/2014\/02\/New_cover_bipyBPh-1024x1024.jpg 1024w, https:\/\/ourlocality.org\/mansellresearch\/files\/2014\/02\/New_cover_bipyBPh-624x624.jpg 624w, https:\/\/ourlocality.org\/mansellresearch\/files\/2014\/02\/New_cover_bipyBPh.jpg 1200w\" sizes=\"auto, (max-width: 300px) 100vw, 300px\" \/><\/a><\/p>\n<p><strong>N-heterocyclic stannylene chemistry<\/strong><br \/>\nSynthesis (<a href=\"http:\/\/dx.doi.org\/10.1021\/ic801479g\" target=\"_blank\"><em>Inorg. Chem.<\/em>, <strong>2008<\/strong><\/a>) and transition metal coordination chemistry (<a href=\"http:\/\/dx.doi.org\/10.1021\/ic101920x\" target=\"_blank\"><em>Inorg. Chem.<\/em>, <strong>2011<\/strong><\/a>) of new and thermally robust N-heterocyclic stannylenes (University of Bristol, with C. Russell and D. Wass)<br \/>\n<a href=\"http:\/\/ourlocality.org\/mansellresearch\/files\/2014\/02\/bridge2.jpg\"><img loading=\"lazy\" decoding=\"async\" src=\"http:\/\/ourlocality.org\/mansellresearch\/files\/2014\/02\/bridge2-300x300.jpg\" alt=\"Underneath\" width=\"300\" height=\"300\" class=\"size-medium wp-image-21\" srcset=\"https:\/\/ourlocality.org\/mansellresearch\/files\/2014\/02\/bridge2-300x300.jpg 300w, https:\/\/ourlocality.org\/mansellresearch\/files\/2014\/02\/bridge2-150x150.jpg 150w, https:\/\/ourlocality.org\/mansellresearch\/files\/2014\/02\/bridge2-624x624.jpg 624w, https:\/\/ourlocality.org\/mansellresearch\/files\/2014\/02\/bridge2.jpg 1000w\" sizes=\"auto, (max-width: 300px) 100vw, 300px\" \/><\/a><\/p>\n<p><strong>Trimethylsilylphosphaalkyne<\/strong><br \/>\nA new synthetic route (<a href=\"http:\/\/dx.doi.org\/10.1016\/j.crci.2010.03.031\" target=\"_blank\"><em>Compt. Rend. Chim.<\/em>, <strong>2010<\/strong><\/a>) allowed the first exploration of the coordination chemistry of trimethylsilylphosphaalkyne (<a href=\"http:\/\/dx.doi.org\/10.1039\/c2dt31756g\" target=\"_blank\"><em>Dalton Trans.<\/em>, <strong>2012<\/strong><\/a>, University of Bristol, with M. Green and C. Russell)<br \/>\n<a href=\"http:\/\/ourlocality.org\/mansellresearch\/files\/2014\/02\/gogo4.jpg\"><img loading=\"lazy\" decoding=\"async\" src=\"http:\/\/ourlocality.org\/mansellresearch\/files\/2014\/02\/gogo4-300x300.jpg\" alt=\"gogo4\" width=\"300\" height=\"300\" class=\"alignnone size-medium wp-image-181\" srcset=\"https:\/\/ourlocality.org\/mansellresearch\/files\/2014\/02\/gogo4-300x300.jpg 300w, https:\/\/ourlocality.org\/mansellresearch\/files\/2014\/02\/gogo4-150x150.jpg 150w, https:\/\/ourlocality.org\/mansellresearch\/files\/2014\/02\/gogo4-624x624.jpg 624w, https:\/\/ourlocality.org\/mansellresearch\/files\/2014\/02\/gogo4.jpg 1000w\" sizes=\"auto, (max-width: 300px) 100vw, 300px\" \/><\/a><\/p>\n","protected":false},"excerpt":{"rendered":"<p>Uranium for small molecule activation Uranium-mediated reduction and binding of arenes followed by C-H activation upon addition of a borane (Nature Chem., 2012, University of Edinburgh with P. Arnold and L. Maron) Research into low-valent uranium chemistry that activates dinitrogen, carbon monoxide and carbon dioxide (J. Am. Chem. Soc., 2011, University of Edinburgh, with P. [&hellip;]<\/p>\n","protected":false},"author":286,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":{"footnotes":""},"class_list":["post-157","page","type-page","status-publish","hentry"],"_links":{"self":[{"href":"https:\/\/ourlocality.org\/mansellresearch\/wp-json\/wp\/v2\/pages\/157","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/ourlocality.org\/mansellresearch\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/ourlocality.org\/mansellresearch\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/ourlocality.org\/mansellresearch\/wp-json\/wp\/v2\/users\/286"}],"replies":[{"embeddable":true,"href":"https:\/\/ourlocality.org\/mansellresearch\/wp-json\/wp\/v2\/comments?post=157"}],"version-history":[{"count":15,"href":"https:\/\/ourlocality.org\/mansellresearch\/wp-json\/wp\/v2\/pages\/157\/revisions"}],"predecessor-version":[{"id":183,"href":"https:\/\/ourlocality.org\/mansellresearch\/wp-json\/wp\/v2\/pages\/157\/revisions\/183"}],"wp:attachment":[{"href":"https:\/\/ourlocality.org\/mansellresearch\/wp-json\/wp\/v2\/media?parent=157"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}